By R. Přibil, R. Belcher, H. Freiser
Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and comparable compounds. This ebook additionally considers the “passive” position of those ingredients, that's, their screening (masking) homes, which drastically increase the selectivity of the reactions in universal use.
This textual content comprises six chapters prepared into sections. the 1st half bargains with the makes use of of EDTA and its derivatives in a few fields of chemical research. After supplying an summary of the background at the back of the improvement of EDTA as an analytical reagent, this e-book discusses to the character of equilibria of complexes and the tools utilized in their research. the following bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions by way of natural reagents. The bankruptcy on colorimetry encompasses a part on “colored complexing agents,” which are used additionally in colorimetric determinations of a few parts. this article concludes via comparing using EDTA as a overlaying agent in colorimetry.
This ebook should be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.
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Extra resources for Analytical Applications of EDTA and Related Compounds
J . . 1 , . , 1000 λ, mμ F I G . 16. Molar extinction coefficient ε of the Ni^+EDTA complex. 009MHC1O4, (c) = in 0-018MHC1O4, ( d ) = i n 0025 Μ H Q O 4 . ) THE NATURE OF EQUILIBRIA OF COMPLEXES AND METHODS OF STUDY 39 C o m p o u n d s A a n d Β form AB„ A + «B ^ AB„ (N) and this will have a much stronger absorption at a certain wavelength than any one of its original components. e. e. 77) The stoicheiometric relation is thus determined by plotting the extinction coefficient of the solutions against the mole fraction of one component.
4 4 . SCHWARZENBACH, G . and ACKERMANN, H . , Hel^. chim. acta 3 0 , 1 7 9 9 ( 1 9 4 7 ) . 4 5 . CHAPMAN, D . , / . Chem. Soc. 1 9 5 5 , 1 7 6 6 . 4 6 . PECSOK, R . L . , / . Chem. Educ. 29, 5 9 7 ( 1 9 5 2 ) . 4 7 . BR»iTznsiGER, Η . and HESSE, G . , Z . anorg. Chem. 2 4 9 , 1 1 3 ( 1 9 4 2 ) . 4 8 . BRWÍTZINGER, H . , THIELE, H . and MÍÍLLER, U . , Z . anorg. chem. 2 5 1 , 2 8 5 ( 1 9 4 3 ) . 4 9 . B R n ^ z n i G E R , H . , Z . anorg. Chem. 256, 6 5 ( 1 9 4 8 ) . 5 0 . SCHWARZENBACH, G . , Helv.
The exception is the zinc complex in an ammoniacal solution. Where only ammonia, without a larger a m m o n i u m ion concentration, is present in addition to the complex, a Polarographie wave for zinc will not be produced. In a 1m N H 3 , 1m N H 4 C I solution, however, a Polarographie wave appears which is smaller than the wave of the zinc ion in the same solution in the absence of E D T A . This wave, which corresponds to reduction of the zinc ammine complex has a more negative half-wave potential than that of zinc in ammoniacal solution only.
Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser